| ID | Name | Country | District | Population |
| 661 | Murcia | Spain | Murcia | 353,504 |
| 662 | Palma de Mallorca | Spain | Balears | 326,993 |
| 663 | Valladolid | Spain | Castilla and León | 319,998 |
| 664 | Córdoba | Spain | Andalusia | 311,708 |
| 665 | Vigo | Spain | Galicia | 283,670 |
| 666 | Alicante [Alacant] | Spain | Valencia | 272,432 |
| 667 | Gijón | Spain | Asturia | 267,980 |
| 668 | L´Hospitalet de Llobregat | Spain | Katalonia | 247,986 |
| 669 | Granada | Spain | Andalusia | 244,767 |
| 670 | A Coruña (La Coruña) | Spain | Galicia | 243,402 |
| 671 | Vitoria-Gasteiz | Spain | Baskimaa | 217,154 |
| 672 | Santa Cruz de Tenerife | Spain | Canary Islands | 213,050 |
| 673 | Badalona | Spain | Katalonia | 209,635 |
| 674 | Oviedo | Spain | Asturia | 200,453 |
| 675 | Móstoles | Spain | Madrid | 195,351 |
| 676 | Elche [Elx] | Spain | Valencia | 193,174 |
| 677 | Sabadell | Spain | Katalonia | 184,859 |
| 678 | Santander | Spain | Cantabria | 184,165 |
| 679 | Jerez de la Frontera | Spain | Andalusia | 182,660 |
| 680 | Pamplona [Iruña] | Spain | Navarra | 180,483 |